A voltammetric electronic tongue as tool for water quality monitoring in wastewater treatment plants
Identifieur interne : 000293 ( Main/Exploration ); précédent : 000292; suivant : 000294A voltammetric electronic tongue as tool for water quality monitoring in wastewater treatment plants
Auteurs : Inmaculada Campos [Espagne] ; Miguel Alcaniz [Espagne] ; Daniel Aguado [Espagne] ; Ram N Barat [Espagne] ; José Ferrer [Espagne] ; Luis Gil [Espagne] ; Mouna Marrakchi [Tunisie] ; Ram N Martinez-Manez [Espagne] ; Juan Soto [Espagne] ; José-Luis Vivancos [Espagne]Source :
- Water research : (Oxford) [ 0043-1354 ] ; 2012.
Descripteurs français
- Pascal (Inist)
- Qualité eau, Surveillance, Station épuration, Prédiction, Effluent, Eau usée, Anaérobie, Bioréacteur, Réacteur membrane, Eau usée domestique, Epuration eau usée, Argent, Nickel, Cuivre, Sulfate, Ammonium, Analyse corrélation, Pollution, DCO, DBO, Ammoniac, Epuration biologique, Composé du soufre, Composé de l'azote, Toxique, Affluent.
- Wicri :
English descriptors
- KwdEn :
- Ammonia, Ammonium, Anaerobe, Biological oxygen demand, Biological purification, Bioreactor, Chemical oxygen demand, Copper, Correlation analysis, Domestic waste water, Effluent, Membrane reactor, Nickel, Nitrogen compounds, Poison, Pollution, Prediction, Sewage treatment plant, Silver, Sulfates, Sulfur compounds, Surveillance, Waste water, Waste water purification, Water quality.
Abstract
The use of a voltammetric electronic tongue as tool for the prediction of concentration levels of certain water quality parameters from influent and effluent wastewater from a Submerged Anaerobic Membrane Bioreactor pilot plant applied to domestic wastewater treatment is proposed here. The electronic tongue consists of a set of noble (Au, Pt, Rh, Ir, and Ag) and non-noble (Ni, Co and Cu) electrodes that were housed inside a stainless steel cylinder which was used as the body of the electronic tongue system. As a previous step an electrochemical study of the response of the ions sulphate, orthophosphate, acetate, bicarbonate and ammonium was carried out in water using the electrodes contained in the electronic tongue. The second part of the work was devoted to the application of the electronic tongue to the characterization of the influent and effluent waters from the wastewater treatment plant. Partial Least Squares analysis was used to obtain a correlation between the data from the tongue and the pollution parameters measured in the laboratory such as soluble chemical oxygen demand (CODs), soluble biological oxygen demand (BODs), ammonia (NH4-N), orthophosphate (PO4-P), Sulphate (SO4-S), acetic acid (HAC) and alkalinity (Alk). A total of 28 and 11 samples were used in the training and the validation steps, respectively, for both influent and effluent water samples. The electronic tongue showed relatively good predictive power for the determination of BOD, COD, NH4-N, PO4-P, SO4-S, and Alk.
Affiliations:
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Mixta Universidad Politécnica de Valencia, Universidad de Valencia</s1><s2>Valencia</s2><s3>ESP</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ><sZ>10 aut.</sZ></inist:fA14><country>Espagne</country><wicri:noRegion>Valencia</wicri:noRegion></affiliation><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Departamento de Química, Universidad Politécnica de Valencia, Camino de Vera s/n</s1><s2>46022, Valencia</s2><s3>ESP</s3><sZ>1 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>Espagne</country><wicri:noRegion>46022, Valencia</wicri:noRegion></affiliation></author><author><name sortKey="Vivancos, Jose Luis" sort="Vivancos, Jose Luis" uniqKey="Vivancos J" first="José-Luis" last="Vivancos">José-Luis Vivancos</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Centro de Reconocimiento Molecular y Desarrollo Tecnológico (IDM), Unidad Mixta Universidad Politécnica de Valencia, Universidad de Valencia</s1><s2>Valencia</s2><s3>ESP</s3><sZ>1 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wicri:level="1"><inist:fA14 i1="01"><s1>Centro de Reconocimiento Molecular y Desarrollo Tecnológico (IDM), Unidad Mixta Universidad Politécnica de Valencia, Universidad de Valencia</s1><s2>Valencia</s2><s3>ESP</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ><sZ>10 aut.</sZ></inist:fA14><country>Espagne</country><wicri:noRegion>Valencia</wicri:noRegion></affiliation><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Departamento de Química, Universidad Politécnica de Valencia, Camino de Vera s/n</s1><s2>46022, Valencia</s2><s3>ESP</s3><sZ>1 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>Espagne</country><wicri:noRegion>46022, Valencia</wicri:noRegion></affiliation><affiliation wicri:level="1"><inist:fA14 i1="06"><s1>CIBER de Bioingeniería, Biomateriales y Nanomedicina (CIBER-BBN)</s1><s3>ESP</s3><sZ>1 aut.</sZ><sZ>8 aut.</sZ><sZ>10 aut.</sZ></inist:fA14><country>Espagne</country><wicri:noRegion>CIBER de Bioingeniería, Biomateriales y Nanomedicina (CIBER-BBN)</wicri:noRegion></affiliation></author><author><name sortKey="Alcaniz, Miguel" sort="Alcaniz, Miguel" uniqKey="Alcaniz M" first="Miguel" last="Alcaniz">Miguel Alcaniz</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Centro de Reconocimiento Molecular y Desarrollo Tecnológico (IDM), Unidad Mixta Universidad Politécnica de Valencia, Universidad de Valencia</s1><s2>Valencia</s2><s3>ESP</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ><sZ>10 aut.</sZ></inist:fA14><country>Espagne</country><wicri:noRegion>Valencia</wicri:noRegion></affiliation><affiliation wicri:level="2"><inist:fA14 i1="03"><s1>Departamento de Ingeniería Electrónica, Universidad Politécnica de Valencia, Camino de Vera s/n</s1><s2>46022 Valencia</s2><s3>ESP</s3><sZ>2 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Espagne</country><placeName><region nuts="2" type="communauté">Communauté valencienne</region></placeName></affiliation></author><author><name sortKey="Aguado, Daniel" sort="Aguado, Daniel" uniqKey="Aguado D" first="Daniel" last="Aguado">Daniel Aguado</name><affiliation wicri:level="2"><inist:fA14 i1="04"><s1>Instituto de Ingeniería del Agua y Medio Ambiente, Universidad Politécnica de Valencia, Camino de Vera s/n</s1><s2>46022 Valencia</s2><s3>ESP</s3><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>Espagne</country><placeName><region nuts="2" type="communauté">Communauté valencienne</region></placeName></affiliation></author><author><name sortKey="Barat, Ram N" sort="Barat, Ram N" uniqKey="Barat R" first="Ram N" last="Barat">Ram N Barat</name><affiliation wicri:level="2"><inist:fA14 i1="04"><s1>Instituto de Ingeniería del Agua y Medio Ambiente, Universidad Politécnica de Valencia, Camino de Vera s/n</s1><s2>46022 Valencia</s2><s3>ESP</s3><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>Espagne</country><placeName><region nuts="2" type="communauté">Communauté valencienne</region></placeName></affiliation></author><author><name sortKey="Ferrer, Jose" sort="Ferrer, Jose" uniqKey="Ferrer J" first="José" last="Ferrer">José Ferrer</name><affiliation wicri:level="2"><inist:fA14 i1="04"><s1>Instituto de Ingeniería del Agua y Medio Ambiente, Universidad Politécnica de Valencia, Camino de Vera s/n</s1><s2>46022 Valencia</s2><s3>ESP</s3><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>Espagne</country><placeName><region nuts="2" type="communauté">Communauté valencienne</region></placeName></affiliation></author><author><name sortKey="Gil, Luis" sort="Gil, Luis" uniqKey="Gil L" first="Luis" last="Gil">Luis Gil</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Centro de Reconocimiento Molecular y Desarrollo Tecnológico (IDM), Unidad Mixta Universidad Politécnica de Valencia, Universidad de Valencia</s1><s2>Valencia</s2><s3>ESP</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ><sZ>10 aut.</sZ></inist:fA14><country>Espagne</country><wicri:noRegion>Valencia</wicri:noRegion></affiliation><affiliation wicri:level="2"><inist:fA14 i1="03"><s1>Departamento de Ingeniería Electrónica, Universidad Politécnica de Valencia, Camino de Vera s/n</s1><s2>46022 Valencia</s2><s3>ESP</s3><sZ>2 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Espagne</country><placeName><region nuts="2" type="communauté">Communauté valencienne</region></placeName></affiliation></author><author><name sortKey="Marrakchi, Mouna" sort="Marrakchi, Mouna" uniqKey="Marrakchi M" first="Mouna" last="Marrakchi">Mouna Marrakchi</name><affiliation wicri:level="1"><inist:fA14 i1="05"><s1>Laboratoire d'Ecologie et Technologie Microbienne, INSAT, Centre Urbain Nord, BP676</s1><s2>1080 Tunis</s2><s3>TUN</s3><sZ>7 aut.</sZ></inist:fA14><country>Tunisie</country><placeName><settlement type="city">Tunis</settlement><region nuts="2">Gouvernorat de Tunis</region></placeName></affiliation></author><author><name sortKey="Martinez Manez, Ram N" sort="Martinez Manez, Ram N" uniqKey="Martinez Manez R" first="Ram N" last="Martinez-Manez">Ram N Martinez-Manez</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Centro de Reconocimiento Molecular y Desarrollo Tecnológico (IDM), Unidad Mixta Universidad Politécnica de Valencia, Universidad de Valencia</s1><s2>Valencia</s2><s3>ESP</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ><sZ>10 aut.</sZ></inist:fA14><country>Espagne</country><wicri:noRegion>Valencia</wicri:noRegion></affiliation><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Departamento de Química, Universidad Politécnica de Valencia, Camino de Vera s/n</s1><s2>46022, Valencia</s2><s3>ESP</s3><sZ>1 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>Espagne</country><wicri:noRegion>46022, Valencia</wicri:noRegion></affiliation><affiliation wicri:level="1"><inist:fA14 i1="06"><s1>CIBER de Bioingeniería, Biomateriales y Nanomedicina (CIBER-BBN)</s1><s3>ESP</s3><sZ>1 aut.</sZ><sZ>8 aut.</sZ><sZ>10 aut.</sZ></inist:fA14><country>Espagne</country><wicri:noRegion>CIBER de Bioingeniería, Biomateriales y Nanomedicina (CIBER-BBN)</wicri:noRegion></affiliation></author><author><name sortKey="Soto, Juan" sort="Soto, Juan" uniqKey="Soto J" first="Juan" last="Soto">Juan Soto</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Centro de Reconocimiento Molecular y Desarrollo Tecnológico (IDM), Unidad Mixta Universidad Politécnica de Valencia, Universidad de Valencia</s1><s2>Valencia</s2><s3>ESP</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ><sZ>10 aut.</sZ></inist:fA14><country>Espagne</country><wicri:noRegion>Valencia</wicri:noRegion></affiliation><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Departamento de Química, Universidad Politécnica de Valencia, Camino de Vera s/n</s1><s2>46022, Valencia</s2><s3>ESP</s3><sZ>1 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ></inist:fA14><country>Espagne</country><wicri:noRegion>46022, Valencia</wicri:noRegion></affiliation></author><author><name sortKey="Vivancos, Jose Luis" sort="Vivancos, Jose Luis" uniqKey="Vivancos J" first="José-Luis" last="Vivancos">José-Luis Vivancos</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Centro de Reconocimiento Molecular y Desarrollo Tecnológico (IDM), Unidad Mixta Universidad Politécnica de Valencia, Universidad de Valencia</s1><s2>Valencia</s2><s3>ESP</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>6 aut.</sZ><sZ>8 aut.</sZ><sZ>9 aut.</sZ><sZ>10 aut.</sZ></inist:fA14><country>Espagne</country><wicri:noRegion>Valencia</wicri:noRegion></affiliation><affiliation wicri:level="1"><inist:fA14 i1="06"><s1>CIBER de Bioingeniería, Biomateriales y Nanomedicina (CIBER-BBN)</s1><s3>ESP</s3><sZ>1 aut.</sZ><sZ>8 aut.</sZ><sZ>10 aut.</sZ></inist:fA14><country>Espagne</country><wicri:noRegion>CIBER de Bioingeniería, Biomateriales y Nanomedicina (CIBER-BBN)</wicri:noRegion></affiliation><affiliation wicri:level="2"><inist:fA14 i1="07"><s1>Departamento de Proyectos de Ingeniería, Universidad Politécnica de Valencia, Camino de Vera s/n</s1><s2>46022 Valencia</s2><s3>ESP</s3><sZ>10 aut.</sZ></inist:fA14><country>Espagne</country><placeName><region nuts="2" type="communauté">Communauté valencienne</region></placeName></affiliation></author></analytic><series><title level="j" type="main">Water research : (Oxford)</title><title level="j" type="abbreviated">Water res. : (Oxf.)</title><idno type="ISSN">0043-1354</idno><imprint><date when="2012">2012</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">Water research : (Oxford)</title><title level="j" type="abbreviated">Water res. : (Oxf.)</title><idno type="ISSN">0043-1354</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Ammonia</term><term>Ammonium</term><term>Anaerobe</term><term>Biological oxygen demand</term><term>Biological purification</term><term>Bioreactor</term><term>Chemical oxygen demand</term><term>Copper</term><term>Correlation analysis</term><term>Domestic waste water</term><term>Effluent</term><term>Membrane reactor</term><term>Nickel</term><term>Nitrogen compounds</term><term>Poison</term><term>Pollution</term><term>Prediction</term><term>Sewage treatment plant</term><term>Silver</term><term>Sulfates</term><term>Sulfur compounds</term><term>Surveillance</term><term>Waste water</term><term>Waste water purification</term><term>Water quality</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Qualité eau</term><term>Surveillance</term><term>Station épuration</term><term>Prédiction</term><term>Effluent</term><term>Eau usée</term><term>Anaérobie</term><term>Bioréacteur</term><term>Réacteur membrane</term><term>Eau usée domestique</term><term>Epuration eau usée</term><term>Argent</term><term>Nickel</term><term>Cuivre</term><term>Sulfate</term><term>Ammonium</term><term>Analyse corrélation</term><term>Pollution</term><term>DCO</term><term>DBO</term><term>Ammoniac</term><term>Epuration biologique</term><term>Composé du soufre</term><term>Composé de l'azote</term><term>Toxique</term><term>Affluent</term></keywords><keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Eau usée</term><term>Argent</term><term>Nickel</term><term>Cuivre</term><term>Pollution</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The use of a voltammetric electronic tongue as tool for the prediction of concentration levels of certain water quality parameters from influent and effluent wastewater from a Submerged Anaerobic Membrane Bioreactor pilot plant applied to domestic wastewater treatment is proposed here. The electronic tongue consists of a set of noble (Au, Pt, Rh, Ir, and Ag) and non-noble (Ni, Co and Cu) electrodes that were housed inside a stainless steel cylinder which was used as the body of the electronic tongue system. As a previous step an electrochemical study of the response of the ions sulphate, orthophosphate, acetate, bicarbonate and ammonium was carried out in water using the electrodes contained in the electronic tongue. The second part of the work was devoted to the application of the electronic tongue to the characterization of the influent and effluent waters from the wastewater treatment plant. Partial Least Squares analysis was used to obtain a correlation between the data from the tongue and the pollution parameters measured in the laboratory such as soluble chemical oxygen demand (CODs), soluble biological oxygen demand (BODs), ammonia (NH<sub>4</sub>-N), orthophosphate (PO<sub>4</sub>-P), Sulphate (SO<sub>4</sub>-S), acetic acid (HAC) and alkalinity (Alk). A total of 28 and 11 samples were used in the training and the validation steps, respectively, for both influent and effluent water samples. The electronic tongue showed relatively good predictive power for the determination of BOD, COD, NH<sub>4</sub>-N, PO<sub>4</sub>-P, SO<sub>4</sub>-S, and Alk.</div></front></TEI><affiliations><list><country><li>Espagne</li><li>Tunisie</li></country><region><li>Communauté valencienne</li><li>Gouvernorat de Tunis</li></region><settlement><li>Tunis</li></settlement></list><tree><country name="Espagne"><noRegion><name sortKey="Campos, Inmaculada" sort="Campos, Inmaculada" uniqKey="Campos I" first="Inmaculada" last="Campos">Inmaculada Campos</name></noRegion><name sortKey="Aguado, Daniel" sort="Aguado, Daniel" uniqKey="Aguado D" first="Daniel" last="Aguado">Daniel Aguado</name><name sortKey="Alcaniz, Miguel" sort="Alcaniz, Miguel" uniqKey="Alcaniz M" first="Miguel" last="Alcaniz">Miguel Alcaniz</name><name sortKey="Alcaniz, Miguel" sort="Alcaniz, Miguel" uniqKey="Alcaniz M" first="Miguel" last="Alcaniz">Miguel Alcaniz</name><name sortKey="Barat, Ram N" sort="Barat, Ram N" uniqKey="Barat R" first="Ram N" last="Barat">Ram N Barat</name><name sortKey="Campos, Inmaculada" sort="Campos, Inmaculada" uniqKey="Campos I" first="Inmaculada" last="Campos">Inmaculada Campos</name><name sortKey="Campos, Inmaculada" sort="Campos, Inmaculada" uniqKey="Campos I" first="Inmaculada" last="Campos">Inmaculada Campos</name><name sortKey="Ferrer, Jose" sort="Ferrer, Jose" uniqKey="Ferrer J" first="José" last="Ferrer">José Ferrer</name><name sortKey="Gil, Luis" sort="Gil, Luis" uniqKey="Gil L" first="Luis" last="Gil">Luis Gil</name><name sortKey="Gil, Luis" sort="Gil, Luis" uniqKey="Gil L" first="Luis" last="Gil">Luis Gil</name><name sortKey="Martinez Manez, Ram N" sort="Martinez Manez, Ram N" uniqKey="Martinez Manez R" first="Ram N" last="Martinez-Manez">Ram N Martinez-Manez</name><name sortKey="Martinez Manez, Ram N" sort="Martinez Manez, Ram N" uniqKey="Martinez Manez R" first="Ram N" last="Martinez-Manez">Ram N Martinez-Manez</name><name sortKey="Martinez Manez, Ram N" sort="Martinez Manez, Ram N" uniqKey="Martinez Manez R" first="Ram N" last="Martinez-Manez">Ram N Martinez-Manez</name><name sortKey="Soto, Juan" sort="Soto, Juan" uniqKey="Soto J" first="Juan" last="Soto">Juan Soto</name><name sortKey="Soto, Juan" sort="Soto, Juan" uniqKey="Soto J" first="Juan" last="Soto">Juan Soto</name><name sortKey="Vivancos, Jose Luis" sort="Vivancos, Jose Luis" uniqKey="Vivancos J" first="José-Luis" last="Vivancos">José-Luis Vivancos</name><name sortKey="Vivancos, Jose Luis" sort="Vivancos, Jose Luis" uniqKey="Vivancos J" first="José-Luis" last="Vivancos">José-Luis Vivancos</name><name sortKey="Vivancos, Jose Luis" sort="Vivancos, Jose Luis" uniqKey="Vivancos J" first="José-Luis" last="Vivancos">José-Luis Vivancos</name></country><country name="Tunisie"><region name="Gouvernorat de Tunis"><name sortKey="Marrakchi, Mouna" sort="Marrakchi, Mouna" uniqKey="Marrakchi M" first="Mouna" last="Marrakchi">Mouna Marrakchi</name></region></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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